The spectral dependencies of the optical rotatory power (ORP-rho) and
the Verdet coefficient (V) of undoped and Fe- and Cr-doped Bi12SiO20 (
BSO) crystals are studied in the spectral range of 440-800 nm. The res
ults show that Cr decreases rho about 4-5% in the range 600-700 nm, bu
t below 560 nm rho strongly increases up to 180-200% compared to the O
RP of undoped BSO, which could be related to the earlier observed abso
rption spectra. Like the ORP, the values of V are lower by about 1-3%
at 700-600 nm, whereas below 590 nm V increases about 2%. The influenc
e of Fe on rho and V strongly depends on the dopant concentration. For
example, at larger concentrations (2.2 mol%) rho and V decrease up to
4% and 12%, respectively, whereas at 0.9 mol% Fe rho and V increase 3
% and 9%, respectively. The influence of the annealing and the illumin
ation on the gyrotropy of undoped BSO are also studied. Some assumptio
n about the nature of the sillenite optical and magneto-optical rotati
on are made. The possibilities to use these materials for fiber optic
magnetic field sensors or to improve their characteristics for photore
fractive applications are discussed, too.