NMR SPECTRAL STUDIES OF DIMEDONE-ALDEHYDE ADDUCTS .2. H-1 AND C-13 NMR-STUDIES OF THE ADDUCTS

Authors
CREMLYN RJ OSBORNE AG WARMSLEY JF
Citation
Rj. Cremlyn et al., NMR SPECTRAL STUDIES OF DIMEDONE-ALDEHYDE ADDUCTS .2. H-1 AND C-13 NMR-STUDIES OF THE ADDUCTS, SPECT ACT A, 52(11), 1996, pp. 1433-1454
Citations number
29
Categorie Soggetti
Spectroscopy
Journal title
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY → ACNP
ISSN journal
13861425
Volume
52
Issue
11
Year of publication
1996
Pages
1433 - 1454
Database
ISI
SICI code
1386-1425(1996)52:11<1433:NSSODA>2.0.ZU;2-6
Abstract
A detailed study of the 270 MHz H-1 and 67 MHz C-13 NMR spectra of fou r series of dimedone adducts and ''anhydrides'' is presented. A valuab le (5)J(HH) homoallylic coupling has been identified which has facilit ated signal locations utilising 2D HETCOR and COLOC experiments. Some earlier spectral assignments are revised.