STUDIES ON THE LITHIUM ION CONDUCTION IN CA0.95LI0.10WO4 USING COLD NEUTRON RADIOGRAPHY

Citation
M. Kamata et al., STUDIES ON THE LITHIUM ION CONDUCTION IN CA0.95LI0.10WO4 USING COLD NEUTRON RADIOGRAPHY, Solid state ionics, 91(3-4), 1996, pp. 303-306
Citations number
5
Categorie Soggetti
Physics, Condensed Matter","Chemistry Physical
Journal title
ISSN journal
01672738
Volume
91
Issue
3-4
Year of publication
1996
Pages
303 - 306
Database
ISI
SICI code
0167-2738(1996)91:3-4<303:SOTLIC>2.0.ZU;2-#
Abstract
Cold neutron radiography (CNR) was applied to study the lithium ion co nduction in the substituted scheelite-type oxide of Ca0.95Li0.10WO4. T he lithium ion distribution profiles were obtained from a set of neutr on radiography (NR) images of the electrolyzed oxides having different Li-6/Li-7 ratios. They showed that the lithium ion transport number o f the oxide is 0.99, which coincided with the value derived from the E MF measurement of an oxygen gas concentration cell. Furthermore, they denoted that the lithium ion conduction was preferably ascribed to lit hium ions in the interstitial sites.