M. Kamata et al., STUDIES ON THE LITHIUM ION CONDUCTION IN CA0.95LI0.10WO4 USING COLD NEUTRON RADIOGRAPHY, Solid state ionics, 91(3-4), 1996, pp. 303-306
Cold neutron radiography (CNR) was applied to study the lithium ion co
nduction in the substituted scheelite-type oxide of Ca0.95Li0.10WO4. T
he lithium ion distribution profiles were obtained from a set of neutr
on radiography (NR) images of the electrolyzed oxides having different
Li-6/Li-7 ratios. They showed that the lithium ion transport number o
f the oxide is 0.99, which coincided with the value derived from the E
MF measurement of an oxygen gas concentration cell. Furthermore, they
denoted that the lithium ion conduction was preferably ascribed to lit
hium ions in the interstitial sites.