Citation
E. Bacque et al., SYNTHESIS OF DISILYMETHANES AND POLYSILACARBOSILANES, PRECURSORS OF SILICON CARBIDE-BASED MATERIALS, Journal of organometallic chemistry, 521(1-2), 1996, pp. 99-107
Citations number
58
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
ISSN journal
0022328X
Volume
521
Issue
1-2
Year of publication
1996
Pages
99 - 107
Database
ISI
SICI code
0022-328X(1996)521:1-2<99:SODAPP>2.0.ZU;2-U
Abstract
Using a new procedure, substituted disilylmethanes have been prepared
from chlorosilanes, dichloromethane, and magnesium in tetrahydrofuran.
Bis(chlorosilyl)methanes can be used as comonomers for the synthesis
of polysilacarbosilanes, which are transformed into polycarbosilanes,
precursors of silicon carbide.