OXIDATION OF STERICALLY HINDERED ORGANOSILICON HYDRIDES USING POTASSIUM-PERMANGANATE

Authors
LICKISS PD LUCAS R
Citation
Pd. Lickiss et R. Lucas, OXIDATION OF STERICALLY HINDERED ORGANOSILICON HYDRIDES USING POTASSIUM-PERMANGANATE, Journal of organometallic chemistry, 521(1-2), 1996, pp. 229-234
Citations number
18
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
521
Issue
1-2
Year of publication
1996
Pages
229 - 234
Database
ISI
SICI code
0022-328X(1996)521:1-2<229:OOSHOH>2.0.ZU;2-Q
Abstract
The one-pot synthesis of Ph(3)SiOH, (t)Bu(2)Si(OH)(2), (Me(3)Si)(3)CSi (OH)(3) and (Me(3)Si)(3)CSiMe(2)OH directly from the corresponding bul ky silicon hydrides using KMnO4 is described. The size of the substitu ents, the silane:KMnO4 stoichiometry, the solvent and the application of ultrasound were all shown to influence the rate of the reactions.