BICL3-CATALYZED MUKAIYAMA-ALDOL AND CARBONYL-ENE REACTIONS

Authors
PEIDRO L LEROUX C LAPORTERIE A DUBAC J
Citation
L. Peidro et al., BICL3-CATALYZED MUKAIYAMA-ALDOL AND CARBONYL-ENE REACTIONS, Journal of organometallic chemistry, 521(1-2), 1996, pp. 397-399
Citations number
28
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
521
Issue
1-2
Year of publication
1996
Pages
397 - 399
Database
ISI
SICI code
0022-328X(1996)521:1-2<397:BMACR>2.0.ZU;2-G
Abstract
The H-ene pathway has not been detected for the bismuth(III) chloride- catalyzed Mukaiyama-aldol reaction involving silyl enol ethers and ald ehydes. The silatropic ene-like process is the only mechanism observed , even with the weakly reactive 1-(trimethylsilyloxy) cyclohexene. How ever, trimerization of an aliphatic aldehyde can occur.