SYNTHESIS AND CHARACTERIZATION OF A NEW GALLOPHOSPHATE (MU-1) CONTAINING COBALTICINIUM CATIONS

Authors
KALLUS S PATARIN J MARLER B
Citation
S. Kallus et al., SYNTHESIS AND CHARACTERIZATION OF A NEW GALLOPHOSPHATE (MU-1) CONTAINING COBALTICINIUM CATIONS, Microporous materials, 7(2-3), 1996, pp. 89-95
Citations number
18
Categorie Soggetti
Chemistry Physical","Material Science","Chemistry Applied
Journal title
Microporous materials → ACNP
ISSN journal
09276513
Volume
7
Issue
2-3
Year of publication
1996
Pages
89 - 95
Database
ISI
SICI code
0927-6513(1996)7:2-3<89:SACOAN>2.0.ZU;2-8
Abstract
The use of bis(cyclopentadienyl)cobalt(III) ion (Cp(2)Co)(+) in the sy stem Ga2O3-P2O5-HF-H2O was investigated. A new gallophosphate consisti ng of (Cp(2)Co)(+) cations and Ga4P4O12(OH)(8) D4R units hosting F- an ions was obtained. It is structurally closely related to a gallophosph ate previously prepared in the presence of dabconium cations. The mate rial was characterized by elemental analysis, SEM, XRD, thermal analys is and solid state NMR spectroscopy.