THE KINETIC-STUDY OF MULTISTEP ELECTRODE PROCESSES AT MICROELECTRODESUNDER STEADY-STATE CONDITIONS

A general current-potential expression for the first order EE reaction s at disk and spherical microelectrodes on the basis of the equal flux es under steady-state conditions was derived. According to the classif ication for the voltammetric experiment that presented in our previous work, the characteristics of the E(r)E(r), E(q)E(r), E(i)E(r), E(r)E( q), E(r)E(i), E(i)E(i), E(q)E(q) and EE(infinity) mechanisms are also discussed, Obviously, it expressed the electrode processes in concept more concisely. In this work, we also presented some methods for the d etermination of kinetic parameters in various systems and examplified by the reduction of thionyl chloride (SOCl2) in dimethyl formamide (DM F).