S. Migita et al., THE INFLUENCE OF BI-STICKING COEFFICIENT IN THE GROWTH OF BI(2212) THIN-FILM BY ION-BEAM SPUTTERING, Thin solid films, 282(1-2), 1996, pp. 510-512
BSCCO thin films are fabricated via a co-deposition process by an ion
beam sputtering method with an ultra-low growth rate, and sticking coe
fficients of the respective elements are evaluated. The sticking coeff
icient of Bi element exhibits a characteristic temperature dependence;
almost a constant value of 0.49 below 730 degrees C and decreases lin
early with temperature over 730 degrees C. This temperature dependence
can be elucidated from the evaporation and sublimation rates of bismu
th oxide, Bi2O3, from the film surface. It is considered that the liqu
id phase of the bismuth oxide plays an important role in the Bi(2212)
phase formation in the co-deposition process.