One of the major problems hindering the application of porous Si to el
ectroluminescent devices is the high resistance of the electrode/porou
s Si contact. To overcome the problem, we anodized the alloyed Pt/Si c
ontacts to form porous alloyed Pt/Si contacts and studied the chemical
compositions and photoluminescence (PL). The porous alloyed Pt/Si con
tact exposed to the 488 nm line of the Ar ion laser light exhibits red
-light emission (600-800 nm). The composition of the contact strongly
depends on the alloying temperature, The PL spectra are similar to tha
t of porous Si without Pt, and the peak wavelength is affected by the
annealing process. However, the PL intensity is lower than that of por
ous Si without Pt. This is either due to the subsurface layer with the
Pt,Si phase keeping the Si layer underneath From being anodized or ke
eping the emitted light from coming out of the surface. The I-V charac
teristic of the porous alloyed Pt/Si contact demonstrates a good ohmic
contact with a low contact resistance.