ON THE PHOTOELECTRON-SPECTRUM OF LI-4(-)

Authors
BAUSCHLICHER CW
Citation
Cw. Bauschlicher, ON THE PHOTOELECTRON-SPECTRUM OF LI-4(-), Chemical physics letters, 260(1-2), 1996, pp. 309-313
Citations number
18
Categorie Soggetti
Physics, Atomic, Molecular & Chemical
Journal title
Chemical physics letters → ACNP
ISSN journal
00092614
Volume
260
Issue
1-2
Year of publication
1996
Pages
309 - 313
Database
ISI
SICI code
0009-2614(1996)260:1-2<309:OTPOL>2.0.ZU;2-9
Abstract
The most stable structure for Li-4(-) is found to be the rhombus. Elec tron detachment from this structure does not seem able to fully explai n the experimental photoelectron spectrum. The computed results are co nsistent with those of Rao, Jena, and Ray, who have proposed that the experimental spectrum consists of a superposition of detachment from t he Li-4(-) rhombus(B-2(2n)) and tetrahedron ((4)A(1)), forming the sin glet and tripler states of Li-4, respectively.