THERMAL-CONVERSION OF 1-ALKYNYL-1,2-DIHYDROPHOSPHETES INTO PHOSPHININES

Authors
AVARVARI N LEFLOCH P CHARRIER C MATHEY F
Citation
N. Avarvari et al., THERMAL-CONVERSION OF 1-ALKYNYL-1,2-DIHYDROPHOSPHETES INTO PHOSPHININES, Heteroatom chemistry, 7(5), 1996, pp. 397-402
Citations number
15
Categorie Soggetti
Chemistry
Journal title
Heteroatom chemistry → ACNP
ISSN journal
10427163
Volume
7
Issue
5
Year of publication
1996
Pages
397 - 402
Database
ISI
SICI code
1042-7163(1996)7:5<397:TO1IP>2.0.ZU;2-1
Abstract
1-Alkynyl-1,2-dihydrophosphetes, as prepared by reaction of the approp riate titanacyclobutenes with alkynyldichlorophosphines, rearrange to the corresponding phosphinines via an original 4 pi-cycloreversion-6 p i-electrocyclization mechanism. The reaction of dimethyltitanocene wit h 1,4-diphenylbutadiyne affords a new 3-vinyltitanacyclobut-3-ene that can serve to prepare a 3-vinylphosphinine 6 by the same route. (C) 19 96 John Wiley & Sons, Inc.