STUDY ON THE OXIDATION MECHANISM OF MIXED THIOLS IN LIGHT OIL SWEETENING .2. KINETICS AND MECHANISM OF CATALYTIC COOXIDATION OF MIXED THIOLS IN GAS-LIQUID SYSTEM
Dh. Xia et al., STUDY ON THE OXIDATION MECHANISM OF MIXED THIOLS IN LIGHT OIL SWEETENING .2. KINETICS AND MECHANISM OF CATALYTIC COOXIDATION OF MIXED THIOLS IN GAS-LIQUID SYSTEM, Fuel science & technology international, 14(9), 1996, pp. 1205-1218
Kinetic measurements were carried out for the catalytic cooxidation of
mixed 1-butanethiol, 1-octanethiol and 2-methyl-2-propanethiol in gas
-liquid system. A mechanism which can explain the enhancement of the o
xidation of 2-methyl-2-propanethiol by normal thiols and agree well wi
th the experimental results was set up, and the Michaelis-Menten type
kinetic equation was derived accordingly. Researches also demonstrate
that the interactions between different thiol molecules during the cat
alytic cooxidation of mixed thiols in the sweetening process are the g
eneral role.