STUDIES ON THE SYNTHESIS OF METHYL-5-O-BE NZOYL-2,3-DIDEOXY-3-NITRO-D-PENTAFURANOSIDE

Citation
Dq. Shi et al., STUDIES ON THE SYNTHESIS OF METHYL-5-O-BE NZOYL-2,3-DIDEOXY-3-NITRO-D-PENTAFURANOSIDE, Gaodeng xuexiao huaxue xuebao, 17(10), 1996, pp. 1586-1588
Citations number
6
Categorie Soggetti
Chemistry
ISSN journal
02510790
Volume
17
Issue
10
Year of publication
1996
Pages
1586 - 1588
Database
ISI
SICI code
0251-0790(1996)17:10<1586:SOTSOM>2.0.ZU;2-F
Abstract
The synthesis of methyl-5-O-benzoyl-2,3-dideoxy-3-nitro-alpha-and beta -D-pentafuranoside 1a and 1b from D-(+)-xylose is described. The four isomers, the intermediates for synthesis of 1a and 1b, methyl-5-O-benz oyl-3-deoxy-3-nitro-D-ribo and D-xylo, alpha, beta-pentofuranoside 7a, 7b, 7c and 7d were separated and identified. The isomerization of C-3 nitro group of compounds 6, 7 were studied.