F. Kifanisahban et al., DETERMINATION OF KINETIC-PARAMETERS OF SL OW PYROLYSIS OF MOROCCAN EUCALYPTUS WOOD, Thermochimica acta, 289(1), 1996, pp. 33-40
In the present paper, the kinetic parameters of the slow pyrolysis of
Moroccan eucalyptus wood, a species frequently used in the traditional
manufacture of charcoal, are determined by thermogravimetry. The kine
tic parameters of Eucalyptus are compared to those of xylan, cellulose
and lignin. The Coats-Redfern integral method is used to evaluate the
thermogravimetric data obtained. The kinetic plots of xylan, cellulos
e and lignin give a single line whereas eucalyptus gives a dual-segmen
t. The results obtained show that the activation energy of the first s
tep of the degradation of eucalyptus is lower than the activation ener
gy of the second step. Taking into account, on the one hand, the decom
position intervals of xylan and cellulose, and on the other, the fact
that lignin decomposes in the entire temperature interval studied, we
interpret the pyrolysis of eucalyptus as being the decomposition of li
gnin accompanied by that of hemicellulose during the first stage, and
by that of cellulose during the second stage.