We have studied the unimolecular evaporation of ionized lithium cluste
rs for different conditions of ionization. In this article we present
the total evaporative rates and the monomer-dimer branching ratios for
Li-11(+). We observe nonstatistical effects, associated with the diss
ociation along a less energetically favorable channel. Even after a fe
w microseconds, the internal energy is probably not statistically dist
ributed in all the vibrational modes.