ON THE FISSION OF CHARGED ALKALI-METAL CLUSTERS

Citation
A. Rigo et al., ON THE FISSION OF CHARGED ALKALI-METAL CLUSTERS, Surface review and letters, 3(1), 1996, pp. 617-621
Citations number
27
Categorie Soggetti
Physics, Condensed Matter","Physics, Atomic, Molecular & Chemical","Material Science
Journal title
ISSN journal
0218625X
Volume
3
Issue
1
Year of publication
1996
Pages
617 - 621
Database
ISI
SICI code
0218-625X(1996)3:1<617:OTFOCA>2.0.ZU;2-3
Abstract
A deformed jellium model is used to calculate the fission barrier heig ht of Na-24(2+) --> Na-21(+) + Na-3(+) within the Kohn-Sham density-fu nctional theory (i.e., including shell effects). Although the shape of the barrier obviously depends on the parametrization of the fission p ath, we have found that the saddle point corresponds to a configuratio n in which the emerging fragments are already formed and rather well a part. From this result, we offer a simple way to calculate the barrier height for charged trimer emission from alkali-metal clusters of (alm ost) arbitrarily large size and charge state.