REACTIONS OF MONOVALENT METAL-IONS (M(-ABLATION MOLECULAR-BEAM (LAMB)METHOD - PREFERRED OR NONSPECIFIC COORDINATION()) WITH MIXED MOLECULAR CLUSTERS (NH3)(M)(H2O)(N) AS STUDIED BY LASER)
H. Sato et al., REACTIONS OF MONOVALENT METAL-IONS (M(-ABLATION MOLECULAR-BEAM (LAMB)METHOD - PREFERRED OR NONSPECIFIC COORDINATION()) WITH MIXED MOLECULAR CLUSTERS (NH3)(M)(H2O)(N) AS STUDIED BY LASER), Surface review and letters, 3(1), 1996, pp. 671-674
Three distinct types of competitive solvation around monopositive meta
l ions in the gas phase have been revealed by the laser-ablation molec
ular beam method using binary clusters in the molecular beam: (i) pref
erred solvation of one of the two components, (ii) essentially nonsele
ctive solvation, and (iii) magic-number-like behavior of one component
in the presence of the other component in the outer solvation sphere.