The electronic structures of Sb, Ni, and Au clusters of nanometer size
are discussed. Clusters were deposited on a graphite substrate and an
alyzed with a scanning tunneling microscope in an ultrahigh-vacuum sys
tem. Scanning at constant-current mode at different bias voltages was
used as a method of spectroscopic measurements. Disappearing of the cl
usters images at certain range of voltage biases is attributed to occu
rrence of the energy gap in electronic structure of clusters, suggesti
ng their nonmetallic behavior.