The composition of {0001} surfaces of 6H-SiC samples was studied by us
ing low-energy electron diffraction, Auger electron (AES), and X-ray p
hotoelectron spectroscopy (XPS/SXPS). The samples were cleaned in ultr
ahigh vacuum by heating them either in the presence of a Si flux at di
fferent temperatures or by annealing at 1170 K for 10 min. Depending o
n the preparation method and temperature used four reconstructions wer
e observed: (1x1), (3x3), (root 3x root 3)R30 degrees, and (6 root 3x6
root 3)R30 degrees. The compositions of the reconstructions and the c
hemical bonding of the surface atoms were characterized using AES and
XPS/SXPS. Models for the reconstructions are proposed.