Au, C and Sb clusters of nanometer size deposited on silicon and graph
ite substrates are investigated by means of a scanning tunnelling micr
oscopy (STM). Both deposition and measurements were carried out in an
ultrahigh vacuum (UHV) system at room temperature. The apparent height
of the clusters, which reflects not only geometry but also their elec
tronic density of states, changes markedly while scanning at different
voltage biases. Such behaviour depends significantly on the cluster s
ize, their chemical composition and the type of substrate. We discuss
the properties of clusters in terms of their size and modifications by
the substrate.