A SIMPLE CATALYTIC-SYSTEM FOR THE SUBSTITUTIVE CARBONYLATION OF ALLYLALCOHOLS TO BETA,GAMMA-UNSATURATED ACIDS OR ESTERS

Authors
GABRIELE B SALERNO G COSTA M CHIUSOLI GP
Citation
B. Gabriele et al., A SIMPLE CATALYTIC-SYSTEM FOR THE SUBSTITUTIVE CARBONYLATION OF ALLYLALCOHOLS TO BETA,GAMMA-UNSATURATED ACIDS OR ESTERS, Journal of molecular catalysis. A, Chemical, 111(1-2), 1996, pp. 43-48
Citations number
37
Categorie Soggetti
Chemistry Physical
Journal title
Journal of molecular catalysis. A, Chemical → ACNP
ISSN journal
13811169
Volume
111
Issue
1-2
Year of publication
1996
Pages
43 - 48
Database
ISI
SICI code
1381-1169(1996)111:1-2<43:ASCFTS>2.0.ZU;2-U
Abstract
Allyl alcohols can be efficiently carbonylated to beta,gamma-unsaturat ed acids or esters in dimethylacetamide (DMA) or MeOH/DMA mixtures und er relatively mild conditions (80 degrees C, 50-100 atm) using a simpl e catalytic system consisting of palladium iodide in the presence of t hiourea as ligand. In the case of but-2-ene-1,4-diol, selectivation to methyl 5-hydroxypent-3-enoate, 3,6-dihydro-1,2-pyrone or dimethyl hex -3-enedioate may be achieved.