J. Kapala et al., THERMODYNAMIC ACTIVITIES AND PHASE BOUNDARIES FOR THE ALLOYS OF THE NI3AL-NI3TI PSEUDOBINARY SECTION IN THE NI-AL-TI SYSTEM, Metallurgical and materials transactions. A, Physical metallurgy andmaterials science, 27(9), 1996, pp. 2673-2677
The pseudobinary section Ni3Al-Ni3Ti of the ternary Ni-Al-Ti system ha
s been investigated by thermal analysis and Knudsen effusion mass spec
trometry. The solidus of the pseudobinary section and the thermodynami
c activities of Ni and Al have been determined in the alloys Ni0.75Al0
.25Tix of the compositions x = 0.00 to 0.21. Moreover, the thermodynam
ic activities of Ni and Ti in Ni3Ti (x = 0.25) as well as the Gibbs en
ergy of mixing of the Ni0.75Ti0.25 phase resulted. The ionization cros
s-sectional ratio sigma(Ni)/sigma(Ti) = 0.77 has been evaluated for th
e electron impact energy of 50 eV.