Fs. Spear et Rr. Parrish, PETROLOGY AND COOLING RATES OF THE VALHALLA COMPLEX, BRITISH-COLUMBIA, CANADA, Journal of Petrology, 37(4), 1996, pp. 733-765
Rocks from the Valhalla metamorphic core complex, British Columbia, Ca
nada, have experienced granulite facies metamorphism at conditions of
820 +/- 30 degrees C, 8 +/- 1 kbar. Peak metamorphism teas accompanied
by dehydration melting of muscovite, but not biotite, followed by min
or back reaction of garnet + K-feldspar + H2O = sillimanite + biotite
+ plagioclase. At conditions very near those of the peak, extensive sh
earing produced s-c (schistosite-cisaillement) fabrics, ribbon quartz
and grain size reduction of garnet at several locations. Garnet-biotit
e Fe-Mg exchange thermometry yields temperatures that range from 580 t
o 1051 degrees C. Low temperatures are calculated from biotite modifie
d dominantly by Fe-Mg exchange with garnet; high temperatures are calc
ulated from Fe-rich biotites produced from the above retrograde reacti
on. Geothermometry is useless in these rocks to estimate peak temperat
ure a priori, but is very useful to help constrain the complex reactio
n history of biotites. Geochronology on monazite, zircon, allanite, ti
tanite, hornblende, muscovite, biotite and apatite has been used to co
nstrain the timing of the metamorphic peak at 67-72 Ma and the average
cooling rate to 24 +/- 6 degrees C/Ma. Diffusion modeling of Fe-Mg ex
change between biotite inclusions and host garnet yields cooling rates
of either 3-80 degrees C/Ma or 200-2500 degrees C/Ma, depending on th
e choice of diffusion coefficients. The former value is consistent wit
h the average cooling rate of 24 degrees C/Ma for the complex determin
ed from geochronology, but the faster rate cannot be ruled out and may
indicate initial very rapid cooling by thrusting of the complex onto
cooler basement. It is suggested that cooling rates determined from ge
ochronologic vs petrologic methods may not be directly comparable beca
use petrologic methods sample near-peak metamorphic cooling rates wher
eas geochronologic methods sample post-peak to ambient cooling rates.