INTERACTION OF HEXAFLUOROPROPENE TRIMERS WITH AMMONIA AND PRIMARY AMINES

Hexafluoropropene trimers (HFPT) react with primary amines to form the corresponding enamines and enimines, i.e. products arising from the i ndirect substitution of fluorine atoms. The adduct with HFPT has been obtained for the first time in the reaction with ammonia. The intramol ecular cyclization of the compounds synthesized to give azetines and a zetidines has been studied. Specific features of the F-19 NMR spectra of the enimines obtained have been considered.