DETERMINATION OF REACTIVITY RATIOS FOR ETHYLENE ALPHA-OLEFIN COPOLYMERIZATION CATALYZED BY THE C2H4[IND]2ZRCL2/METHYLALUMINOXANE SYSTEM/

Authors
GALLAND GB QUIJADA P MAULER RS DEMENEZES SC
Citation
Gb. Galland et al., DETERMINATION OF REACTIVITY RATIOS FOR ETHYLENE ALPHA-OLEFIN COPOLYMERIZATION CATALYZED BY THE C2H4[IND]2ZRCL2/METHYLALUMINOXANE SYSTEM/, Macromolecular rapid communications, 17(9), 1996, pp. 607-613
Citations number
9
Categorie Soggetti
Polymer Sciences
Journal title
Macromolecular rapid communications → ACNP
ISSN journal
10221336
Volume
17
Issue
9
Year of publication
1996
Pages
607 - 613
Database
ISI
SICI code
1022-1336(1996)17:9<607:DORRFE>2.0.ZU;2-V
Abstract
The present study reports values of reactivity ratios for ethylene/1-h exene, ethylene/1-octene and ethylene/1-decene copolymerizations promo ted by C2H4[Ind]2ZrCl2/MAO. The comonomer reactivities are markedly in fluenced by the number of carbon atoms of the alpha-olefin. The ethyle ne/1-decene copolymerization depends on the concentration of alpha-ole fin in the feed.