EFFECT OF ZSM-11 CRYSTALLINITY ON ITS CATALYTIC PERFORMANCE IN BENZENE TO PHENOL OXIDATION WITH NITROUS-OXIDE

Authors
PIRUTKO LV DUBKOV KA SOLOVYEVA LP PANOV GI
Citation
Lv. Pirutko et al., EFFECT OF ZSM-11 CRYSTALLINITY ON ITS CATALYTIC PERFORMANCE IN BENZENE TO PHENOL OXIDATION WITH NITROUS-OXIDE, Reaction kinetics and catalysis letters, 58(1), 1996, pp. 105-110
Citations number
15
Categorie Soggetti
Chemistry Physical
Journal title
Reaction kinetics and catalysis letters → ACNP
ISSN journal
01331736
Volume
58
Issue
1
Year of publication
1996
Pages
105 - 110
Database
ISI
SICI code
0133-1736(1996)58:1<105:EOZCOI>2.0.ZU;2-1
Abstract
Evolution of ZSM-11 zeolite crystal and pore structure has been studie d at 150 degrees C depending on the synthesis time. The amorphous gel was shown to be catalytically inert over the whole induction period, w hich precedes the crystallization process. The concentration of active sites and the catalytic activity in the oxidation of benzene to pheno l is related to the zeolite structure formation and the increasing deg ree of crystallinity.