The relationship between the helical twisting power (HTP) of cholester
ic liquid crystals and the molecular structure of the chiral mesogens
has been investigated. Rod-like mesogens are compared with analogues b
earing a bulky lateral branch. Additionally, the HTP of induced choles
teric phases formed by chiral guest molecules in nematic host phases h
as been studied in terms of different molecular structures. The paper
gives information on the influence of bulky lateral groups in mesogens
on the HTP.