CATALYTIC ASYMMETRIC ALLYLATION OF ALDEHYDES WITH BINOL-TI(IV) COMPLEX ACCELERATED BY I-PRSSIME(3)

Authors
YU CM CHOI HS JUNG WH LEE SS
Citation
Cm. Yu et al., CATALYTIC ASYMMETRIC ALLYLATION OF ALDEHYDES WITH BINOL-TI(IV) COMPLEX ACCELERATED BY I-PRSSIME(3), Tetrahedron letters, 37(39), 1996, pp. 7095-7098
Citations number
23
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
37
Issue
39
Year of publication
1996
Pages
7095 - 7098
Database
ISI
SICI code
0040-4039(1996)37:39<7095:CAAOAW>2.0.ZU;2-F
Abstract
Practical and efficient catalytic asymmetric allylation reaction of ac hiral aldehydes with allyltri-n-butylstannane in the presence of chira l Lewis acid catalyst has been achieved by the use of accelerator, i-P rSSiMe(3). This system exhibited not only dramatically accelerating re activity but also significantly increasing catalytic ability. Copyrigh t (C) 1996 Elsevier Science Ltd