NOVEL SYNTHESIS OF VINYL CYCLOPROPANE CARBOXYLIC-ACIDS - APPLICATION TO THE SYNTHESIS OF (D,L)-CIS-CHRYSANTHEMIC AND (D)-CIS-CHRYSANTHEMIC ACID

Authors
KRIEF A SWINNEN D
Citation
A. Krief et D. Swinnen, NOVEL SYNTHESIS OF VINYL CYCLOPROPANE CARBOXYLIC-ACIDS - APPLICATION TO THE SYNTHESIS OF (D,L)-CIS-CHRYSANTHEMIC AND (D)-CIS-CHRYSANTHEMIC ACID, Tetrahedron letters, 37(39), 1996, pp. 7123-7126
Citations number
16
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
37
Issue
39
Year of publication
1996
Pages
7123 - 7126
Database
ISI
SICI code
0040-4039(1996)37:39<7123:NSOVCC>2.0.ZU;2-W
Abstract
Reaction of sulfur ylides with suitably 4-functionalized-5,5-dimethyl- 2-cyclopentenones allows an efficient entry to the bicyclo[3.1.0]hexan -2-one skeleton which proved to be a valuable precursor of vinyl cyclo propane carboxylic acids, Application to the synthesis of (d,l)- and ( d)-(cis)-chrysanthemic acid is described. Copyright (C) 1996 Elsevier Science Ltd