Sm. Lomakin et Ge. Zaikov, PYROLYSIS AND CARBONIZATION OF CROSS-LINKED POLY(METHYL METHACRYLATE), International journal of polymeric materials, 33(3-4), 1996, pp. 133-140
The thermal degradation of network copolymers of methyl methacrylate w
as studied as a function of the chemistry of me cross-linking agent an
d frequency of cross-links. Unlike the linear homopolymer, both the tr
imethylolpropane triacrylate and trimethylolpropane trimethacrylate ne
tworks were found to char when burned. The differences in the thermal
degradation of these polymers are interpreted in terms of a simple mod
el for kinetics of depolymerization.