KINETIC SCHEME REDUCTION VIA GEOMETRIC SINGULAR PERTURBATION TECHNIQUES

Citation
P. Duchene et P. Rouchon, KINETIC SCHEME REDUCTION VIA GEOMETRIC SINGULAR PERTURBATION TECHNIQUES, Chemical Engineering Science, 51(20), 1996, pp. 4661-4672
Citations number
17
Categorie Soggetti
Engineering, Chemical
ISSN journal
00092509
Volume
51
Issue
20
Year of publication
1996
Pages
4661 - 4672
Database
ISI
SICI code
0009-2509(1996)51:20<4661:KSRVGS>2.0.ZU;2-Q
Abstract
An effective reduction method based on geometric singular perturbation and center manifold techniques is proposed. This method eliminates th e fast and stable dynamics and gives the equations describing the slow ones. It is coordinate-free and extends the well-known quasi-steady-s tate method classically used for kinetic scheme reduction. This yields directly the slow dynamics even if the differential equations are not in standard two time-scale form (Tikhonov form). Application to combu stion kinetics including 13 species and 67 reactions is presented and simulations are given. Copyright (C) 1996 Elsevier Science Ltd