P. Duchene et P. Rouchon, KINETIC SCHEME REDUCTION VIA GEOMETRIC SINGULAR PERTURBATION TECHNIQUES, Chemical Engineering Science, 51(20), 1996, pp. 4661-4672
An effective reduction method based on geometric singular perturbation
and center manifold techniques is proposed. This method eliminates th
e fast and stable dynamics and gives the equations describing the slow
ones. It is coordinate-free and extends the well-known quasi-steady-s
tate method classically used for kinetic scheme reduction. This yields
directly the slow dynamics even if the differential equations are not
in standard two time-scale form (Tikhonov form). Application to combu
stion kinetics including 13 species and 67 reactions is presented and
simulations are given. Copyright (C) 1996 Elsevier Science Ltd