INCLUSION EFFECTS OF CYCLODEXTRINS ON THE CATALYTIC ACTIVITY OF LAMINOMETHYL-1,7,7-TRIMETHYLNORBORNAN-2-ENDO-AMINE FOR THE DECARBOXYLATION OF OXALACETATE

Authors
OGINO K AZUMA H TAMIYA H TAGAKI W
Citation
K. Ogino et al., INCLUSION EFFECTS OF CYCLODEXTRINS ON THE CATALYTIC ACTIVITY OF LAMINOMETHYL-1,7,7-TRIMETHYLNORBORNAN-2-ENDO-AMINE FOR THE DECARBOXYLATION OF OXALACETATE, Perkin transactions. 2, (9), 1996, pp. 2005-2007
Citations number
16
Categorie Soggetti
Chemistry Physical","Chemistry Inorganic & Nuclear
Journal title
Perkin transactions. 2 → ACNP
ISSN journal
03009580
Issue
9
Year of publication
1996
Pages
2005 - 2007
Database
ISI
SICI code
0300-9580(1996):9<2005:IEOCOT>2.0.ZU;2-A
Abstract
The inclusion effects of cyclodextrins (CD) on the catalytic activity of ylaminomethyl-1,7,7-trimethylnorboman-2-endo-amine (DTN) for the de carboxylation of oxalacetate have been studied. It was found that beta -CD, consisting of seven glucose units, showed a marked enhancement of the catalytic activity of DTN by the inclusion, whereas alpha-CD show ed neither inclusion nor enhancement, and gamma-CD showed the inclusio n phenomenon, but only with small enhancement, These observations are discussed in terms of the regulation of the DTN conformation by the in clusion.