SYNTHESIS REACTIVITY AND MOLECULAR-STRUCTURE OF 2'-METHYLSPIRO[CYCLOHEXANE-1,3'-3H-INDOLE] CHROMIUM TRICARBONYL COMPLEX

Authors
RODRIGUEZ JG URRUTIA A FONSECA I SANZ J
Citation
Jg. Rodriguez et al., SYNTHESIS REACTIVITY AND MOLECULAR-STRUCTURE OF 2'-METHYLSPIRO[CYCLOHEXANE-1,3'-3H-INDOLE] CHROMIUM TRICARBONYL COMPLEX, Journal of organometallic chemistry, 522(2), 1996, pp. 231-235
Citations number
17
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
522
Issue
2
Year of publication
1996
Pages
231 - 235
Database
ISI
SICI code
0022-328X(1996)522:2<231:SRAMO2>2.0.ZU;2-Q
Abstract
Synthesis of 2'-methylspiro[cyclohexane-1,3'-3H-indole] chromium trica rbonyl and structural analysis by spectroscopy and single-crystal X-ra y techniques have been carried out. The reactivity of the C=N bond of indolenine with organometallic reagents has also been analysed. The re duction of 2'-methylspiro[cyclohexane-1,3'-3H-indole] chromium tricarb onyl with AILiH(4) gave endo- and exo-complexes, which have been isola ted and analysed by spectroscopic methods.