INTERACTION OF CARBON-DIOXIDE WITH THE BIS(TRIMETHYLSILYL)ACETYLENE COMPLEX OF PERMETHYLTITANOCENE - SYNTHESIS AND STRUCTURE OF THE BINUCLEAR CARBONATE COMPLEX OF PERMETHYLTITANOCENE (CP(2)(ASTERISK)TI)(2)CO3

Authors
BURLAKOV VV DOLGUSHIN FM YANOVSKY AI STRUCHKOV YT SHUR VB ROSENTHAL U THEWALT U
Citation
Vv. Burlakov et al., INTERACTION OF CARBON-DIOXIDE WITH THE BIS(TRIMETHYLSILYL)ACETYLENE COMPLEX OF PERMETHYLTITANOCENE - SYNTHESIS AND STRUCTURE OF THE BINUCLEAR CARBONATE COMPLEX OF PERMETHYLTITANOCENE (CP(2)(ASTERISK)TI)(2)CO3, Journal of organometallic chemistry, 522(2), 1996, pp. 241-247
Citations number
23
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
522
Issue
2
Year of publication
1996
Pages
241 - 247
Database
ISI
SICI code
0022-328X(1996)522:2<241:IOCWTB>2.0.ZU;2-F
Abstract
It has been shown that in the interaction of carbon dioxide with the b is(trimethylsilyl)acetylene complex of permethyltitanocene Cp(2)Ti(Me (3)SiC(2)SiMe(3)), full displacement of bis(trimethylsilyl)acetylene f rom the titanium coordination sphere takes place and carbon dioxide un dergoes disproportionation to form Cp(2)()Ti(CO)(2) and the binuclear carbonate complex of permethyltitanocene (Cp(2)Ti)(2)CO3. The struct ure of (Cp(2)Ti)(2)CO3 has been established by X-ray diffraction stud y. Structural data on the related chlorine-containing carbonate comple x Cp(2)Ti(Cl)CO(3)TiCp(2)* are also reported.