RAPID AND MILD SYNTHESIS OF [RE-2(CO)(10)] BY REDUCTION OF [NH4][REO4] AT ATMOSPHERIC CO PRESSURE

Authors
TOP S MOREL P PANKOWSKI H JAOUEN G
Citation
S. Top et al., RAPID AND MILD SYNTHESIS OF [RE-2(CO)(10)] BY REDUCTION OF [NH4][REO4] AT ATMOSPHERIC CO PRESSURE, Journal of the Chemical Society. Dalton transactions, (17), 1996, pp. 3611-3612
Citations number
15
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of the Chemical Society. Dalton transactions → ACNP
ISSN journal
03009246
Issue
17
Year of publication
1996
Pages
3611 - 3612
Database
ISI
SICI code
0300-9246(1996):17<3611:RAMSO[>2.0.ZU;2-K
Abstract
With a view to accessing radiopharmaceuticals based on Re-186 and Re-1 88, a simple, efficient and rapid synthesis at low CO pressure of the key complex [Re-2(CO)(10)] from [NH4][ReO4] using (Me(2)CHCH(2))(2)AlH in toluene as reducing agent has been obtained.