M. Miyazawa et al., BIOTRANSFORMATION OF ALPHA-TERPINENE IN COMMON CUTWORM LARVAE (SPODOPTERA-LITURA FABRICIUS), Journal of agricultural and food chemistry, 44(9), 1996, pp. 2889-2893
alpha-Terpinene was mixed in an artificial diet at a concentration of
10 mg/g of diet, and the diet was fed to the last instar larvae of com
mon cutworm, Spodoptera litura Fabricius. Metabolites were recovered f
rom frass and analyzed spectroscopically. The alpha-terpinene was tran
sformed mainly to 4-isopropyl-1,3-cyclohexadienoic acid and cumic acid
. The allylic methyl group of alpha-terpinene was preferentially oxidi
zed. The results indicate that the intestinal bacteria probably partic
ipated in the metabolism of alpha-terpinene. The aerobically active in
testinal bacteria transformed alpha-terpinene to 4-isopropyl-1,3-cyclo
hexadienemethanol, and the anaerobically active intestinal bacteria tr
ansformed alpha-terpinene to p-cymene.