A method for measuring the stress tensor of liquids obeying the stress
-optical rule is presented. In particular, the procedure makes it poss
ible to determine the shear stress, and the first and second normal st
ress differences for rheometric flows. This technique is an extension
of the procedure recently described by Burghardt and coworkers (Brown
et al., 1995) wherein light is sent obliquely through a sample sheared
between transparent plates. However, in the present development, the
light is transmitted in the plane containing the velocity gradient and
neutral directions, thereby reducing the necessary optical measuremen
ts by one. A polystyrene-tricresyl phosphate (TCP) solution is used as
the test sample. The first and second normal stress differences in st
eady shear flow measured by this method show good agreement with the m
echanical results measured by Madga et al. (1993) using a modified con
e and plate rheometer. The transient behavior of the first and second
normal stress differences following the start-up of shear flow is also
presented.