SYNTHESIS, STRUCTURE AND MAGNETIC-PROPERTIES OF A POLYMERIC TRINUCLEAR MIXED-VALENCE MANGANESE MALONATE COMPLEX

Authors
WEI YG ZHANG SW SHAO MC LIU Q TANG YQ
Citation
Yg. Wei et al., SYNTHESIS, STRUCTURE AND MAGNETIC-PROPERTIES OF A POLYMERIC TRINUCLEAR MIXED-VALENCE MANGANESE MALONATE COMPLEX, Polyhedron, 15(23), 1996, pp. 4303-4305
Citations number
22
Categorie Soggetti
Chemistry Inorganic & Nuclear",Crystallography
Journal title
Polyhedron → ACNP
ISSN journal
02775387
Volume
15
Issue
23
Year of publication
1996
Pages
4303 - 4305
Database
ISI
SICI code
0277-5387(1996)15:23<4303:SSAMOA>2.0.ZU;2-G
Abstract
A mixed-valence Mn-III, Mn-II, Mn-III malonate polymeric cluster havin g a trimeric repeat unit, {[Mn-II (H2O)(4)] [Mn(malonate)(2) (H2O)](2) }(n), which is the first example of mixed-valence manganese carboxylat e polymeric complex, has been prepared and characterized structurally. This complex behaves as an antiferromagnet and has a Neel temperature of ca 10K. Copyright (C) 1996 Elsevier Science Ltd