VARIABLE-TEMPERATURE MULTIDIMENSIONAL NMR-STUDY OF ANIONIC RH(I) ANILIDO [(R(3)P)(2)RH(NHPH)(2)](-),M(+) COMPLEXES

Authors
BRUNET JJ COMMENGES G NEIBECKER D ROSENBERG L
Citation
Jj. Brunet et al., VARIABLE-TEMPERATURE MULTIDIMENSIONAL NMR-STUDY OF ANIONIC RH(I) ANILIDO [(R(3)P)(2)RH(NHPH)(2)](-),M(+) COMPLEXES, Journal of organometallic chemistry, 522(1), 1996, pp. 117-122
Citations number
22
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
522
Issue
1
Year of publication
1996
Pages
117 - 122
Database
ISI
SICI code
0022-328X(1996)522:1<117:VMNOAR>2.0.ZU;2-Y
Abstract
Variable temperature multidimensional NMR studies of [(R(3)P)(2)Rh(NHP h)(2)](-) Li+ complexes enabled the detection of activation of one aro matic ortho proton of each anilide ligand. This activation is not attr ibutable to a C-H-0-Rh agostic interaction, but rather to interaction with lithium, resulting from a short distance between the lithium atom and one of the aromatic ortho hydrogens of each anilide ligand.