K. Oohira et K. Toko, THEORY OF ELECTRIC CHARACTERISTICS OF THE LIPID PVC/DOPP MEMBRANE ANDPVC/DOPP MEMBRANE IN RESPONSE TO TASTE STIMULI/, Biophysical chemistry, 61(1), 1996, pp. 29-35
Electric characteristics of two kinds of membranes in response to NaCl
and quinine were theoretically studied; one membrane composed of poly
vinyl chloride (PVC) and dioctylphenylphosphonate (DOPP), and the othe
r a lipid/PVC/DOPP membrane containing PVC, DOPP and a negatively char
ged lipid. We develop a theory by taking into account both the surface
electric potential and the diffusion potential within the membrane an
d succeed in interpreting the observed data. On increasing the NaCl co
ncentration, the lipid/PVC/DOPP membrane changes from weakly charged s
tate to fully charged state by dissociation of H+ from the lipids. The
hydrophobic interaction between quinine and the PVC/DOPP membrane was
strong enough to overcome the electric repulsion.