DESIGN, SYNTHESIS, AND ELECTROCHEMICAL-BEHAVIOR OF NEW ELECTRONIC SYSTEMS INVOLVING SIGMA,SIGMA-INTERACTION AND SIGMA,PI-INTERACTION

Authors
NISHIWAKI K YOSHIDA J
Citation
K. Nishiwaki et J. Yoshida, DESIGN, SYNTHESIS, AND ELECTROCHEMICAL-BEHAVIOR OF NEW ELECTRONIC SYSTEMS INVOLVING SIGMA,SIGMA-INTERACTION AND SIGMA,PI-INTERACTION, Chemistry Letters, (9), 1996, pp. 787-788
Citations number
13
Categorie Soggetti
Chemistry
Journal title
Chemistry Letters → ACNP
ISSN journal
03667022
Issue
9
Year of publication
1996
Pages
787 - 788
Database
ISI
SICI code
0366-7022(1996):9<787:DSAEON>2.0.ZU;2-T
Abstract
1,2-Bis(trimethylsilyl)-1,2-diphenylethane and its homologues were syn thesized and the studies on their electrochemical behavior revealed th at there is definite interaction between the sigma,pi-interaction syst em (the C-Si bonds and the benzene rings) and the sigma,sigma-interact ion system (the neighboring C-Si bonds) which causes significant decre ase of the oxidation potentials.