The fibre present in mushroom compost samples was separated by a stand
ard method of selective hydrolysis into three components: acid deterge
nt fibre (ADF), neutral detergent fibre (NDF) and lignin. Results of d
ifferential thermogravimetric (DTG) analysis of these fractions sugges
t that with NDF the matrix polysaccharides were detected as a shoulder
to the cellulose peak and that structural hemicelluloses pyrolysed be
fore the lignin decomposition peak. However, in ADF, only cellulose an
d lignin pyrolysis peaks were detected and a hemicellulose decompositi
on peak or shoulder was not present. In the lignin there were two pyro
lysis peaks which represented residual polysaccharides and lignin. The
rmograms of humus which had been separated from the compost by ultraso
nic treatment showed that microbial polysaccharides and phenolic compo
unds were the main components. Lignin and humus contained high concent
rations of nitrogen compared with the other fractions. Comparison of t
hermograms of uncomposted wheat straw and straw from compost showed th
at straw cell-wall components were altered by fermentation.