A STEREOSELECTIVE SYNTHESIS OF 1,2-DISUBSTITUTED ALKENYL SELENIDES VIA HYDROBORATION-IODINATION OF INTERNAL ALKYLSELENOACETYLENES WITH DICYCLOHEXYLBORANE

Authors
YANG DY HUANG X
Citation
Dy. Yang et X. Huang, A STEREOSELECTIVE SYNTHESIS OF 1,2-DISUBSTITUTED ALKENYL SELENIDES VIA HYDROBORATION-IODINATION OF INTERNAL ALKYLSELENOACETYLENES WITH DICYCLOHEXYLBORANE, Journal of organometallic chemistry, 523(2), 1996, pp. 139-143
Citations number
15
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
523
Issue
2
Year of publication
1996
Pages
139 - 143
Database
ISI
SICI code
0022-328X(1996)523:2<139:ASSO1A>2.0.ZU;2-8
Abstract
Selenoalkenyldicyclohexylboranes, prepared conveniently via hydroborat ion of internal alkylselenoacetylenes with dicyclohexylborane followed by iodination under basic conditions, produce cis/trans 1,2-disubstit uted alkenyl selenides (1 and 2), which provide a general method for s ynthesis of cis/trans disubstituted alkenyl selenides containing a cyc lohexyl group.