COMMENT ON THE INVERSION OF RAMAN EXCITATION PROFILES - REPLY

Authors
Citation
Sy. Lee et Zw. Feng, COMMENT ON THE INVERSION OF RAMAN EXCITATION PROFILES - REPLY, Chemical physics letters, 260(3-4), 1996, pp. 511-513
Citations number
19
Categorie Soggetti
Physics, Atomic, Molecular & Chemical
Journal title
ISSN journal
00092614
Volume
260
Issue
3-4
Year of publication
1996
Pages
511 - 513
Database
ISI
SICI code
0009-2614(1996)260:3-4<511:COTIOR>2.0.ZU;2-8
Abstract
The Raman amplitude when extended into the complex energy plane can ha ve zeros in the right-half plane. Minimum phase approaches to invert t he Raman excitation profile (REP) to recover the Raman amplitude are v alid only for the case where the Raman amplitude does not admit zeros in the right-half plane. A minimum phase algorithm applied to a REP gi ves a unique amplitude, but this amplitude and its corresponding cross -correlation function are wrong if the REP corresponds to a nonminimum phase problem. The minimum phase treatment therefore does not carry a ll possible physical information for a nonminimum phase REP.