ALCL3-DMF REAGENT IN THE FRIEDEL-CRAFTS REACTION - THE BEHAVIOR OF OMEGA-HALOGENOACID CHLORIDES

Authors
POUPAERT JH KANYONYO M UCAR H MOUITHYS AM DIOUF O LESIEUR D
Citation
Jh. Poupaert et al., ALCL3-DMF REAGENT IN THE FRIEDEL-CRAFTS REACTION - THE BEHAVIOR OF OMEGA-HALOGENOACID CHLORIDES, Bulletin des Societes chimiques belges, 105(7), 1996, pp. 397-401
Citations number
12
Categorie Soggetti
Chemistry
Journal title
Bulletin des Societes chimiques belges → ACNP
ISSN journal
00379646
Volume
105
Issue
7
Year of publication
1996
Pages
397 - 401
Database
ISI
SICI code
0037-9646(1996)105:7<397:ARITFR>2.0.ZU;2-M
Abstract
2(3H)-benzoxazolones or 2(3H)-benzothiazolones react at 70-75 degrees C with omega-halogenoacyl chlorides in the presence the AlCl3-DMF comp lex to produce the expected ketones in 55-88 % yield. Treatment of a 2 (3H)-benzoxazolone or 2(3H)-benzothiazolone by 4-chlorobutyryl chlorid e produced an alcohol derivative, presumably via an anchimeric partici pation of the 6-acyl carbonyl moiety.