An approach of using a current-controlled voltage source analogy to ac
count for a general boundary condition of particle or thermal flux in
transmission-line matrix (TLM) diffusion modelling has been developed.
For mass diffusion, this boundary condition is expressed as D partial
derivative C/partial derivative x + alpha C = 0, where C is the conce
ntration, D is the diffusion coefficient, and alpha is a parameter cha
racterizing the out-diffusion mobility across the boundary of interest
. Confirmation of the TLM numerical treatment through comparison with
analytical solutions is presented. Besides the open-circuit and short-
circuit boundaries, the matched-load boundary is also found to be a sp
ecial case of the present boundary condition. This extension of the bo
undary treatment allows the highly flexible TLM method to be applied t
o a greater variety of diffusion problems.