SYNTHESIS, NMR SPECTROSCOPIC STUDIES, AND X-RAY STRUCTURES OF PLATINUM(II) COORDINATION-COMPLEXES OF THE ORGANOPHOSPHORUS CAGE COMPOUNDS P(4)C(4)BU(4)(T) AND P(5)C(5)BU(5)(T)

Authors
CALIMAN V HITCHCOCK PB JONES C NIXON JF
Citation
V. Caliman et al., SYNTHESIS, NMR SPECTROSCOPIC STUDIES, AND X-RAY STRUCTURES OF PLATINUM(II) COORDINATION-COMPLEXES OF THE ORGANOPHOSPHORUS CAGE COMPOUNDS P(4)C(4)BU(4)(T) AND P(5)C(5)BU(5)(T), Phosphorus, sulfur and silicon and the related elements, 113(1-4), 1996, pp. 15-37
Citations number
18
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Phosphorus, sulfur and silicon and the related elements → ACNP
ISSN journal
10426507
Volume
113
Issue
1-4
Year of publication
1996
Pages
15 - 37
Database
ISI
SICI code
1042-6507(1996)113:1-4<15:SNSSAX>2.0.ZU;2-W
Abstract
The first examples of platinum(II) complexes of the P(4)C(4)Bu(4)(t) a nd P(5)C(5)Bu(5)(t) ''cages'' are described and detailed nmr and X-ray crystallographic structural studies have been carried out on the comp lexes trans-[PtCl2(PR(3))(P4C4B4t)], trans-[{PtCl2(PR(3))}(2)(P(4)C(4) Bu(4)(t))], (R=Et, Bu), and trans-[PtCl2(PEt(3))(P(5)C(5)Bu(5)(t))].