DITHIOCARBOXYLATION REACTIONS OF CIS-BICY CLO[3.3.0]OCTANE-3,7-DIONES- MOLECULAR AND CRYSTAL-STRUCTURE OF ETHYLTHIOMETHYLENE)-BICYCLO[3.3.0]OCTANE-3,7-DIONE

Authors
DOLLING W SIEBEL HM BIEDERMANN M HARTUNG H
Citation
W. Dolling et al., DITHIOCARBOXYLATION REACTIONS OF CIS-BICY CLO[3.3.0]OCTANE-3,7-DIONES- MOLECULAR AND CRYSTAL-STRUCTURE OF ETHYLTHIOMETHYLENE)-BICYCLO[3.3.0]OCTANE-3,7-DIONE, Phosphorus, sulfur and silicon and the related elements, 113(1-4), 1996, pp. 263-274
Citations number
23
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Phosphorus, sulfur and silicon and the related elements → ACNP
ISSN journal
10426507
Volume
113
Issue
1-4
Year of publication
1996
Pages
263 - 274
Database
ISI
SICI code
1042-6507(1996)113:1-4<263:DROCC>2.0.ZU;2-1
Abstract
The cis-bicyclo[3.3.0]octane-3,7-dione 1a and its 1,5-dimethyl derivat ive 1b react with carbon disulfide, strong base and an alkylating agen t in dipolar aprotic solvents giving racemic mixtures of 2-dialkylthio methylene compounds 2, whereas in the presence of two equivalents of c arbon disulfide and the appropriate amount of basel and further alkyla ting agent the cis-2,6-bis(dimethylthio-methylene) derivatives 3 are f ormed. The crystal and molecular structure of 3a has been investigated by X-ray analysis.