TRANS-DICHLOROTETRAKIS(PYRIDINE-N)-MOLYBDENUM(III) TRIBROMIDE

Citation
R. Rotar et al., TRANS-DICHLOROTETRAKIS(PYRIDINE-N)-MOLYBDENUM(III) TRIBROMIDE, Acta crystallographica. Section C, Crystal structure communications, 52, 1996, pp. 2155-2157
Citations number
16
Categorie Soggetti
Crystallography
ISSN journal
01082701
Volume
52
Year of publication
1996
Part
9
Pages
2155 - 2157
Database
ISI
SICI code
0108-2701(1996)52:<2155:TT>2.0.ZU;2-T
Abstract
In the title compound, trans-[(MoCl2)-Cl-III(C5H5N)(4)]Br-3, the Cl an d pyridine N atoms define a slightly distorted octahedron around the M o atom. Both cations and anions lie on twofold axes. Pyridine rings wh ich are located trans with respect to one another are staggered. The t ribromide ion, Br-3(-), is essentially linear.